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Transition metal reactivity trend
Transition metal reactivity trend







transition metal reactivity trend

in Comprehensive Organometallic Chemistry III Vol. The Nugent-RajanBabu reagent: a formidable tool in contemporary radical and organometallic chemistry. Titanium(III)-induced cyclization of epoxy olefins. Transition-metal-centered radicals in organic synthesis. Methods utilizing first-row transition metals in natural product total synthesis. Controlled carbometalation as a new tool for carbon-carbon bond formation and its application to cyclization.

transition metal reactivity trend

Zirconium-catalyzed asymmetric carboalumination of unactivated terminal alkenes. in Comprehensive Organic Synthesis II 2nd edn Vol. Conversion of zirconacyclopentadienes into metalloles: Fagan–Nugent reaction and beyond. Metallacycle-mediated cross-coupling with substituted and electronically unactivated alkenes. Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen. Examining the relationship between coordination mode and reactivity of dinitrogen. Dinitrogen functionalization with bis(cyclopentadienyl) complexes of zirconium and hafnium. Side-on end-on bound dinitrogen: an activated bonding mode that facilitates functionalizing molecular nitrogen. Dinitrogen activation by group 4 and group 5 metal complexes supported by phosphine-amido containing ligand manifolds. The continuing story of dinitrogen activation. Activation of nitrogen for organic synthesis. Theoretical, spectroscopic, and mechanistic studies on transition-metal dinitrogen complexes: implications to reactivity and relevance to the nitrogenase problem. Dinitrogen and related chemistry of the lanthanides: a review of the reductive capture of dinitrogen, as well as mono- and di-aza containing ligand chemistry of relevance to known and postulated metal mediated dinitrogen derivatives. Dinitrogen coordination chemistry: on the biomimetic borderlands. Recent advances in the chemistry of dinitrogen complexes. Dinitrogen fixation and activation after 30 years: a puzzle still unsolved. Multimetallic cooperative activation of N 2. A quantitative scale of oxophilicity and thiophilicity. Chemistry of the Elements (Butterworth-Heinemann, Oxford, 1997). J.) 1–28 (Royal Society of Chemistry, 2013). in Elem ent Reco very an d Sustainability (ed.









Transition metal reactivity trend